{N,N-Dimethyl-N′-[phenyl(2-pyridyl)methylene]ethane-1,2-diamine-κ3 N,N′,N′′}dithiocyanato-κN,κS-copper(II)
نویسندگان
چکیده
In the title complex, [Cu(NCS)(2)(C(16)H(19)N(3))], the Cu(II) atom is coordinated by a total of four N atoms; three from one tridentate Schiff base ligand and one from one of the NCS(-) ions. The S atom from the other NCS(-) ion completes the distorted square-pyramidal coordination.
منابع مشابه
Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3 N,N′,N′′}copper(II)
In the title compound, [CuCl(2)(C(11)H(17)N(3))], the Cu(II) ion is five-coordinated with a distorted square-pyramidal configuration. The three N atoms of the Schiff base ligand and one Cl atom are located in the basal plane, whereas the other Cl atom is apically positioned.
متن کاملBromido{N-methyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3 N,N′,N′′}(thiocyanato-κN)copper(II)
In the title mononuclear copper(II) compound, [CuBr(NCS)(C(10)H(15)N(3))], the Cu(II) atom is five-coordinated by three N atoms of the Schiff base ligand, the N atom of a thio-cyanate ligand and by one bromide ion forming a distorted square-pyramidal geometry. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯Br hydrogen bonds into chains propagating along [101].
متن کامل{N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3 N,N′,N′′}bis(thiocyanato-κN)copper(II)
The asymmetric unit of the title compound, [Cu(NCS)(2)(C(11)H(17)N(3))], consists of two crystallographically independent mol-ecules. In each mol-ecule, the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N"-tridentate Schiff base and one N-bound thio-cyanate ligand. The second N-donor thio-cyanate group, located at the apic...
متن کاملAqua{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3 N,N′,N′′}bis(thiocyanato-κN)nickel(II)
In the title compound, [Ni(NCS)(2)(C(11)H(17)N(3))(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothio-cyanate groups and one water mol-ecule. In the crystal, O-H⋯S hydrogen bonds link adjacent mol-ecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C-...
متن کاملDichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3 N,N′,N′′}manganese(II)
The asymmetric unit of the title compound, [MnCl(2)(C(11)H(17)N(3))], contains two crystallographically independent mol-ecules with slightly different geometries. In each mol-ecule, the Mn(II) ion is five coordinated by the N,N',N''-tridentate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. In the crystal, C-H⋯Cl hydrogen bonds link adjacent mol-ecules into a three-dimens...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009